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Unfortunately not necessarily as both PVC and Hypalon have a woven fabric layer in them, which is sometimes referred to as the base layer.
The Hypalon we sell is Orca Pennel & Flipo and typically this has a High Tenacity Polyester 1100 dtex - 990denier base fabric.
The PVC we sell also has a base fabric as shown below.
The fabric layer is not a useful way of determining the material type your inflatable RIB or SIB tubes are made from.